Mesoscopic superstructures of flexible porous coordination polymers synthesized via coordination replication

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Mesoscopic superstructures of flexible porous coordination polymers synthesized via coordination replication.

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Mesoscopic superstructures of flexible porous coordination polymers synthesized via coordination replication† †Electronic supplementary information (ESI) available: Full experimental procedures, powder X-ray diffraction data, thermogravimetric analysis data, adsorption isotherms, scanning electron microscopy data, and additional discussion. See DOI: 10.1039/c5sc02034d Click here for additional data file.

The coordination replication technique is employed for the direct conversion of a macroand mesoporous Cu(OH)2–polyacrylamide composite to three-dimensional superstructures consisting of the flexible porous coordination polymers, Cu2(bdc)2(MeOH)2 and Cu2(bdc)2(bpy) (bdc 2 1⁄4 1,4-benzenedicarboxylate, bpy 1⁄4 4,40-bipyridine). Detailed characterization of the replicated systems reveals that the ...

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ژورنال

عنوان ژورنال: Chemical Science

سال: 2015

ISSN: 2041-6520,2041-6539

DOI: 10.1039/c5sc02034d