Mesoscopic superstructures of flexible porous coordination polymers synthesized via coordination replication
نویسندگان
چکیده
منابع مشابه
Mesoscopic superstructures of flexible porous coordination polymers synthesized via coordination replication.
The coordination replication technique is employed for the direct conversion of a macro- and mesoporous Cu(OH)2-polyacrylamide composite to three-dimensional superstructures consisting of the flexible porous coordination polymers, Cu2(bdc)2(MeOH)2 and Cu2(bdc)2(bpy) (bdc2- = 1,4-benzenedicarboxylate, bpy = 4,4'-bipyridine). Detailed characterization of the replicated systems reveals that the st...
متن کاملChemistry of porous coordination polymers
Remarkable advances in the recent development of porous compounds based upon coordination polymers have paved the way toward functional chemistry having potential applications such as gas storage, separation, and catalysis. From the synthetic point of view, the advantage is a designable framework, which can readily be constructed from building blocks, the so-called bottom-up assembly. Compared ...
متن کاملPolymerization reactions in porous coordination polymers.
Recent developments in polymerizations within the nanochannels of porous coordination polymers (PCPs) are covered in this tutorial review. The characteristic features of PCPs are regular structures, controllable channel sizes and shapes, a designable surface functionality, and flexible frameworks, which can be utilized for precision polymer synthesis and specific polymer confinement. This revie...
متن کاملMesoscopic superstructures of flexible porous coordination polymers synthesized via coordination replication† †Electronic supplementary information (ESI) available: Full experimental procedures, powder X-ray diffraction data, thermogravimetric analysis data, adsorption isotherms, scanning electron microscopy data, and additional discussion. See DOI: 10.1039/c5sc02034d Click here for additional data file.
The coordination replication technique is employed for the direct conversion of a macroand mesoporous Cu(OH)2–polyacrylamide composite to three-dimensional superstructures consisting of the flexible porous coordination polymers, Cu2(bdc)2(MeOH)2 and Cu2(bdc)2(bpy) (bdc 2 1⁄4 1,4-benzenedicarboxylate, bpy 1⁄4 4,40-bipyridine). Detailed characterization of the replicated systems reveals that the ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chemical Science
سال: 2015
ISSN: 2041-6520,2041-6539
DOI: 10.1039/c5sc02034d